When Mimi (Emmanuelle Seigner) follows Oscar at a house party after their break-up, she’s wearing a drab dress and looks very depressed. He mocks her by advising to put some make-up on. She follows the advice by powdering her face.
In the bathroom where Mimi powders her face there are three great perfumes. The first on the left is Hermès Calèche, created by Guy Robert and launched in 1961.
The bottle with drop-shaped stopper is Van Cleef & Arpels First, created by Jean-Claude Ellena and launched in 1976.
Last, Caron Nocturnes de Caron in the fascinating black bottle with round glass stopper. This floral perfume, created by Gerard Lefort, was launched in 1981.
World Wide Aura 
Oh, this is a good one! Curious as to what those black bottles next to the Nocturnes could be — Antaeus and Drakkar Noir, perhaps? Hard to know!
They look like boxes – not bottles – to me. In any case, definitely hard to know!